[Gasification] Universal tar catalyst
Thomas Reed
tombreed at comcast.net
Sun Dec 9 20:16:32 EST 2007
Dear All:
"Tars" sure are the Achilles Heel of biomass gasification,
since biomass
is typically >30% volatiles with slow pyrolysis. Those
volatiles formed
the basis of the development of organic chemistry from
1850-1950. There
are over 50 compounds at greater than 1% in the liquors and
tars. Great
for chemistry but bad for gasification.
In the 1980s many people pursued "catalytic tar destruction"
and we made
tests on a number of catalysts while developing our oxygen
gasifier at
SERI/NREL. (Reported in our book "Air-Oxygen Stratified
Downdraft
Gasification" at woodgas.com).
Dolomite was claimed by many Europeans to be a great and
cheap catalyst
for tar destruction. It was the bottom of our list of half
a dozen
catalysts we tried. I was very puzzled. Is European
Dolomite different
from US?
I haven't heard much about dolomite recently.
Any updates?
TOM REED BEF
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