[Gasification] Cadmium and other heavy metal toxicity
LINVENT at aol.com
LINVENT at aol.com
Thu May 10 19:43:44 CDT 2007
>From the discussion relating to heavy metals and the ones listed as of
concern, all are affected by soil pH, except for Mo, their availability declines
with increasing pH. Mo is just the opposite and Cu is to some degree. However, Cu
is necessary in high organic matter soils for microbes to consume and make
use of the carbon, as are other elements. Application of lime (which typically
contains Pb), will reduce all of the heavy metal effects upon the soil. This
arises from two actions, one is pH increase and the other is that calcium will
bind with all of the metals to render them unavailable to the plant, both in
pure chemical terms and in dilution.
Additionally, limestone releases CO2 which forms voids in the soil which
reduces it's density and allows root propagation. The Ca allows roots to grow in
vast volumes which increases the absorption area of the plant and allows for
more efficient filtration of the toxic from non-toxic elements. Almost any toxic
element will be taken up if a similar valence or molecular weight or
reactivity element is missing.
Aluminum is frequently taken up from the soil as a replacement for other
elements, even at high pH which is not supposed to happen because Al is not
available at below pH 4, but the root environ is in this pH range, regardless of the
surrounding soil pH. Iron has a similar characteristic. Most US foodstuff has
high Al and Fe due to the mismanagement of the soil and reliance on chemical
stimulation of plant growth with nitrogen which has not only plant
construction properties, but also plant stimulation effects, almost similar to some
hormones. This is the reason most US food tastes like cardboard, has a short shelf
life and the reason for genetic engineering, as the plants cannot fend off
pests as a healthy plant would.
There are plants which can absorb Pb, Ni, Co, and perhaps others. I have seen
one plant which had 50% sodium in it's tissues. Some have been specially
raised, bred, hybridized for this purpose. One cabbage family plant was used
successfully to deplete Ni contaminated soils at a major nickel procuer in
Canada. Another one was used to soak up Pb from battery contaminated soils. Once the
plants absorb the toxic compounds, they become a disposal problem.
Gasification is an answer to this problem as the concentration of the toxic compounds in
the ash reduces the volume and weight and makes them approach economic
recovery.
Latteritic soils in South American rain forests occur becuase the high rain
leaches the cations Ca, Mg, K from the soil leaving aluminum which quickly
binds forming a solid impermeable soil which cannot be used for farming or tree
growing for years. This is easliy fixed.
Toxicity can be defined as an imbalance. Plant nutrition is a very complex
science and knowing how to deal with it makes it an invaluable asset.
Sincerely,
Leland T. "Tom" Taylor
Leland T. "Tom" Taylor
President
Agronics Inc.
7100-E 2nd St. NW
Albuquerque, New Mexico 87107
Phone:505-463-8422
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